Identification and Comparative Analysis of Alkaloids by Inversion Voltammetry Method
Авторы: Semenova V.A., Petrenko E.M. | Опубликовано: 15.12.2019 |
Опубликовано в выпуске: #6(87)/2019 | |
DOI: 10.18698/1812-3368-2019-6-113-121 | |
Раздел: Химия | Рубрика: Электрохимия | |
Ключевые слова: inversion voltammetry, identification, multisensors, electrochemical test system, alkaloids |
The alkaloids concurrent detection and identification in the samples by the method of multisensory inversion voltammetry is the purpose of the work. To achieve this goal, the proposed method has been substantiated, the composition of the electrochemical test system has been optimized taking into account the specifics of the detected substances, and informative signs that characterize the presence of alkaloids in the studied sample have been found. A new approach, consisting in the use of an electrochemical multisensor test system in the form of a solution containing a set of metal ions that can form complex compounds with organic substances, has been developed and scientifically approved. The results showed that each organic substance has a different effect on the electrochemical behavior of the multisensory test system. The use of such a test system made it possible to model the principle currently defined by the term "Electronic tongue". An electronic database has been prepared according to the results of the electroanalytical studies, which made it possible to identify the detected substance by comparing it with analyzed sample. The proposed electrochemical method, which is based on multisensor inversion voltammetry, allows the detection and identification of both narcotic drugs and psychotropic substances with high confidence for a small mass of the sample
Литература
[1] Gaevskiy A.V., Simonov E.A., Sorokin V.I. [Analytical examination of hazardous substances]. Sb. tez. Vseros. konf. "Khimicheskiy analiz veshchestv i materialov" [Abs. Russ. conf. "Chemical Analysis of Substances and Materials"]. Moscow, 2000, pp. 1--9 (in Russ.).
[2] Gaevskiy A.V., Degtyarev E.V., Simonov E.A., et al. Methodology and legal aspects of chemical analysis of hazardous substances. Zavodskaya laboratoriya. Diagnostika materialov [Industrial Laboratory. Diagnostics of Materials], 2000, vol. 66, no. 6, pp. 56--63 (in Russ.).
[3] Simonov E.A., Makarov V.G. Ispolzovanie metodov kapelnogo analiza dlya obnaruzheniya narkoticheskikh sredstv vo vnelaboratornykh usloviyakh. Kriminalistika: 21 vek [Using methods of drip analysis for the detection of narcotic drugs in non-laboratory conditions. In: Forensic Science: 21st Century]. Moscow, EKTs MVD RF Publ., 2001.
[4] Singliar M. Plynova chromatografia v praxi. Bratislava, Slov. vyd. techn. lit., 1961.
[5] Ayvazov B.V. Vvedenie v khromatografiyu [Introduction to chromatography]. Moscow, Vysshaya shkola Publ., 1983.
[6] Polyakova A.A., Khmelnitskiy R.A. Mass-spektrometriya v organicheskoy khimii [Mass spectrometry in organic chemistry]. Leningrad, Khimiya Publ., 1972.
[7] Vulfson N.S., Zaikin V.G., Mikaya A.I. Mass-spektrometriya organicheskikh soedineniy [Mass spectrometry of organic compounds]. Moscow, Khimiya Publ., 1986.
[8] Braynina X.Z., Neyman E.Ya., Slepushkin V.V. Inversionnye elektroanaliticheskie metody [Inversion electroanalytical methods]. Moscow, Khimiya Publ., 1988.
[9] Budnikov G.K., Maystrenko V.N., Vyaselev M.R. Osnovy sovremennogo elektrokhimicheskogo analiza [Fundamentals of modern electrochemical analysis]. Moscow, Mir Publ., Binom Publ., 2003.
[10] Lukovtsev V.P., Doronin A.N., Lukovtseva N.V., et al. Identification of alkaloids using the stripping voltammetry method. Russ. J. Electrochem., 2009, vol. 45, iss. 7, pp. 810--812. DOI: https://doi.org/10.1134/S1023193509070167
[11] Vydra F., Stulik K., Julakova E. Rozpousteci polarog rafie a voltametrie. Praha, SNTL, 1977.
[12] Budnikov G.K. Determination of trace amounts of substances as a problem of modern analytical chemistry. Sorosovskiy obrazovatelnyy zhurnal, 2000, vol. 6, no. 3, pp. 45--51 (in Russ.).
[13] Budnikov G.K. What are chemical sensors. Sorosovskiy obrazovatelnyy zhurnal, 1998, no. 3, pp. 72--76 (in Russ.).
[14] Lukovtsev V.P., Bobov K.N., Dribinskiy A.V., et al. Portable programmed multifunctional research device. Praktika protivokorrozionnoy zashchity [Theory and Practice of Corrosion Protection], 1999, no. 3, pp. 61--62 (in Russ.).
[15] Doronin A.N., Tikhonova S.V., Semenova V.A., et al. The effect of papaverine on cadmium electrodeposition on glassy carbon electrode modified with mercury. Russ. J. Electrochem., 2012, vol. 48, iss. 9, pp. 941–943. DOI: https://doi.org/10.1134/S1023193512080034