|

Analysis of Acoustic Relaxation Thermodynamic Parameters of Some Nonionic Surfactants and their Solutions

Authors: Mysik S.V. Published: 14.02.2017
Published in issue: #1(70)/2017  
DOI: 10.18698/1812-3368-2017-1-92-102

 
Category: Chemistry | Chapter: Inorganic Chemistry  
Keywords: the acoustic spectrum, sound velocity, sound absorption, micelle forming nonionic surfactant

The study tested the relaxation and thermodynamic parameters of fast and ultrafast processes of some nonionic surfactants and their solutions used in practice. First, we analyzed these parameters, as well as their temperature dependence (in the range between 253 and 333 K) and their dependence on surfactants structure. Then, we calculated the relaxation and thermodynamic parameters according to the acoustic spectra of the sound velocity and absorption in some nonionic surfactants and their solutions in the frequency range from 12 MHz to 2 GHz. Finally, we examined the possible molecular mechanisms of reorganization processes of the investigated surfactants and their solutions.

References

[1] Ratajczak H., Orville-Thomas W.J. On some problems of molecular interaction. Wiley, 1980.

[2] Holmber K., Jonsson B., Kronberg B., Lindman B. Surfactants and polymers in aqueous solutions. John Wiley & Sons, 2002. 562 p.

[3] Greben’kov D.S. Issledovanie relaksatsii model’nogo mitsellyarnogo rastvora [Research relaxation model micellar solution]. St. Petersburg, St. Petersburg State University Publ., 2005. 145 p.

[4] Slyusarev A.V., Persiyanova M.A. Determination of the critical micelle concentration in the aqueous surfactant solutions by Rayleigh scattering of light. Sovremennye naukoemkie tekhnologii [Modern High Technologies], 2013, no. 9, pp. 64-65 (in Russ.).

[5] Husainov R.R. Obosnovanie kombinirovannoy tekhnologii povysheniya nefteotdachi plastov s primeneniem PAV v plazmenno-impul’snoy tekhnologii [Substantiation of the combined technologies improve oil recovery with the use of surfactants in the plasma pulse technology]. St. Petersburg, NMSU "Gornyy ", 2014. 146 p.

[6] Bashkirtseva M.Yu. Kompozitsii na osnove neionogennykh PAV dlya kompleksnogo resheniya zadach povysheniya nefteotdachi, podgotovki i transportirovki vysokovyazkoy nefti. Diss. dokt. tekh. nauk [The compositions based on nonionic surfactants for complex problem solving enhanced oil recovery, preparation and transportation of heavy oil. Dr. tech. sci. diss.]. Kazan’, 2009. 360 p.

[7] Shakhparonov M.I. Mekhanizmy bystrykh protsessov v zhidkostyakh [Mechanisms of fast processes in liquids]. Moscow, Vysshaya shkola Publ., 1980. 352 p.

[8] Mysik S.V. Analyzing the acoustic spectra of sound velocity and absorption in the amphiphilic liquids. Nauch.-tekh. vedomosti SPbGPU. Fiz.-Mat. Nauki [St. Petersburg State Poly-technical University Journal. Physics and Mathematics], 2015, iss. 3 (225), pp. 164-172 (in Russ.). DOI: 10.5862/JPM.225.17

[9] Mysik S.V., Shakhparonov M.I. The acoustic properties of the normal decyl alcohol (degree of ethoxylation п = 3) and its solution in dibutyl ether. Vestmk MGU. Khimiya [Bulletin of the Moscow State University. Chemistry], 1986, no. 7779-86, pp. 1-17 (in Russ.).

[10] Mysik S.V., Shakhparonov M.I. The acoustic properties of the normal decyl alcohol (degree of ethoxylation п = 5, 7) and their solution in dibutyl ether. Vestmk MGU. Khimiya [Bulletin of the Moscow State University. Chemistry], 1986, no. 7780-86, pp. 1-20 (in Russ.).

[11] Tseremisin A.N. Vozdeystvie akusticheskogo polya na fil’tratsiyu dvukhfaznoy zhidkosti v poristom kollektore. Diss. kand. tekh. nauk [Influence of the acoustic field in the two-phase fluid filtration in porous reservoir. Cand. tech. sci. diss.]. Tyumen’, 2010. 17 p.

[12] Hlebnikov V.N. Kolloidno-khimicheskie protsessy v tekhnologiyakh povysheniya nefteotdachi. Diss. dokt. tekh. nauk [Colloid-chemical processes in technologies of enhanced oil recovery. Dr. tech. sci. diss.]. Kazan, 2005. 32 p.

[13] Mudzhikova G.V. Modelirovanie obratnykh mitsell metodom molekulyarnoy dinamiki. Diss. kand. khim. nauk [Simulation of reverse micelles by molecular dynamics. Cand. chem. sci. diss.]. St. Petersburg, 2006. 100 p.

[14] Nevidimov A.V. Issledovanie stroeniya obratnykh mitsell metodom molekulyarnoy dinamiki. Diss. kand. khim. nauk [Investigation of reverse micelles by molecular dynamics. Cand. chem. sci. diss.]. Chernogolovka, 2010. 114 p.