Thermodynamic Evaluation of Diamidophosphite Dismutation Capability
Authors: Slitikov P.V. | Published: 22.11.2017 |
Published in issue: #6(75)/2017 | |
DOI: 10.18698/1812-3368-2017-6-96-102 | |
Category: Chemistry | Chapter: Organic Chemistry | |
Keywords: dismutation, diamidophenylphosphites, thermodynamic state functions, NMR-spectroscopy |
This work presents the results of calculations providing the thermodynamic state functions (ΔfHº298, Sº298) for various classes of diamidophenylphosphites, monoamidodiphenylphosphites and full amides of phosphorous acid where the amide group is presented by different secondary amides. The thermodynamic capability of dismutation of diamidophenylphosphites was evaluated according to the calculations of Gibbs energy ΔrGº298 for the corresponding processes. The results of theoretical calculations firmly correlate with the experimental data
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