Production of Chemisorption Polymers and their Thermal Properties
Authors: Romanko O.I. | Published: 12.10.2016 |
Published in issue: #5(68)/2016 | |
DOI: 10.18698/1812-3368-2016-5-115-124 | |
Category: Chemistry | Chapter: Physical Chemistry | |
Keywords: chemisorption, polymers, glass transition temperature, thermal analysis, energy of activation, polymer elasticity |
This article describes a method of chemisorption polymer production based on polyacrylonitrile. Our work provides the calculation of an exchange capacity for this material. Using the thermal analysis we established temperature intervals for molecular and segmental mobility emergence of the polyacrylonitrile copolymers with methallyl sulfonate and 2-methyl-5-vinylpyridine. We determined glass transition temperature and calculated activation energy of glass transition process for the specified copolymers. The data obtained can be used to refine the technological parameters of filter materials production.
References
[1] Zverev O.M. Sewage treatment by fibrous ionites. Vestn. Mosk. Gor. Ped. Univ. Ser. Estestv. Nauki [Vestn. Moscow City Teachers Training Univ., Nat. Sci.], 2014, no. 1 (13), pp. 60-64 (in Russ.).
[2] Berkovich A.K., Sergeev V.G., Medvedev V.A., Malakho A.P. Sintez polimerov na osnove poliakrilonitrila. Tekhnologiya polucheniya PAN i uglerodnykh volokon [Synthesis of polyacrylonitrile-based polymers. The technology of obtaining pan and carbon fibers]. Moscow, Lomonosov Moscow State University Publ., 2010. 63 p.
[3] Petrov Yu.P., Kotyukov A.B., Shcherbinina T.A., Zekhov S.V. The use of CFS and VION materials in water filters. Vestn. Permsk. univ. Geologiya [Bulletin of Perm University. Geology], 2012, iss. 1 (14), pp. 66-67 (in Russ.).
[4] Kvyatkovskaya A.S., Saburova Yu.B., Amirkhanova N.A. Research of anion exchange membrane effectiveness for hexavalent chromium extraction from waste water. Estestv. i mat. nauki v sovremennom mire [Natural and Mathematical Sciences in the Modern World], 2015, vol. 5, no. 29, pp. 20-29 (in Russ.).
[5] Abdulkhakova Z.Z., Zverev O.M. Determination of sorption properties of ion-exchange fibers. Vestn. Mosk. Gor. Ped. Univ. Ser. Estestv. Nauki [Vestn. Moscow City Teachers Training Univ., Nat. Sci., 2013, no. 1 (11), pp. 31-39 (in Russ.).
[6] Dyatlov V.A., Grebeneva T.A., Rustamov I.R., Belokon’ O.V., Kireev V.V., Il’ina M.V. Effect of the polyacrylimide forming copolymers composition on the process of their processing. Vysokomolekulyarnye soedineniya. Ser. A [Polymer Science. Ser. A], 2013, vol. 55, no. 3, pp. 369-374 (in Russ.).
[7] Sil’chenchenkov A.D., Romanko O.I. The principle of obtaining fibrous chemo sorbent for aqueous media purification. Sovremennye estestv.-nauch. i gum. problemy. Nauch.-metod. konf., posvyashchennaya 40-letiyu NUK FN. Sb. trud. [Current natural science and humanitarian problems. Proc. of the scientific-methodical conference devoted to the 40th anniversary of the Research Educational Complex Fundamental Sciences]. Moscow, Logos Publ., 2005, pp. 243-249 (in Russ.).
[8] Dolgova E.V. Sintez i svoystva ionogennykh polimerov i ikh kompleksov s poverkhnostno-aktivnymi veshchestvami v kachestve biotsidnykh materialov. Diss. kand. khim. nauk [Synthesis and properties of ionogenic polymers and their complexes with surfactants as biocidal materials. Cand. chem. sci. diss.]. Moscow, 2015. 154 p. (in Russ.).
[9] Romanko O.I. Phase transformation characteristics in polyoxadiazole. Vestn. Mosk. Gos. Tekh. Univ. im. N.E. Baumana, Estestv. Nauki [Herald of the Bauman Moscow State Tech. Univ., Nat. Sci.], 2015, no. 3, pp. 120-128 (in Russ.). DOI: 10.18698/1812-3368-2015-3-120-128
[10] Romanko O.I. Computation of main kinetic parameters of polymer relaxation. Vestn. Mosk. Gos. Tekh. Univ. im. N.E. Baumana, Estestv. Nauki [Herald of the Bauman Moscow State Tech. Univ., Nat. Sci.], 2004, no. 2, pp. 121-126 (in Russ.).
[11] Kozlov P.V., Papkov S.P. Fiziko-khimicheskie osnovy plastifikatsii polimerov [Physical and chemical bases of plasticizing polymers]. Moscow, Khimiya Publ., 1982. 224 p.
[12] Mitrofanov Yu.P., Lysenko A.V., Lyakhov S.A., Khonik V.A. On the relationship of the shear modulus with activation energy of atomic rearrangements in metallic glasses. Vestnik TGU. Ser. Estestv. i tekh. nauki [Tambov University Reports. Ser. Natural and Technical Sciences], 2010, vol. 15, iss. 3, p. 887 (in Russ.).
[13] Romanko O.I. About structural transformations in flexible-chain of poly-4-methilpentene-1. Abstracts of International Scientific Conference Physical and Mathematical Problems of Advanced Technology Development. Moscow, 2014, р. 99.
[14] Dubrovskiy A.V., Shabarchina L.I., Kim Yu.A., Sukhorukov B.I. Investigation of the influence of temperature on polyelectrolyte microcapsules. Glass Physics and Chemistry, 2007, vol. 33, iss. 3, pp. 226-231. DOI: 10.1134/S1087659607030066
[15] Smirnova N.N., Kulagina A.Yu., Fedotov Yu.A. Effect of temperature on complexation of sulfonate-containing polyphenylenphthalamides and poly-N-(2-aminoethyl) acrylamide in aqueous media. Izv. Vyssh. Uchebn. Zaved., Khimiya i khim. tekhnologiya [Proc. of Higher Educational Institutions. Chemistry and Chemical Technology], 2011, vol. 54, iss. 3, pp. 32-35 (in Russ.).
[16] Golotina L.A., Shardakov I.N. Modeling of polymer’s thermomechanical behavior features in the temperature range including relaxation transition. Vestn. Permsk. Nats. Issled. Politekh. Univ. Mekhanika [PNRPU Mechanics Bulletin], 2010, iss. 3, pp. 49-54 (in Russ.).
[17] Romanko O.I., Shapoval V.N. On the relation of chemical structure and thermal properties of polyimides. Vestn. Mosk. Gos. Tekh. Univ. im. N.E. Baumana, Estestv. Nauki [Herald of the Bauman Moscow State Tech. Univ., Nat. Sci.], 2016, no. 2, pp. 103-113 (in Russ.). DOI: 10.18698/1812-3368-2016-2-103-113