Decryption of diffraction patterns with complex crystal structures using 3D-model of the reciprocal space of crystal lattices
Authors: Zaytsev D.V. | Published: 04.04.2016 |
Published in issue: #2(65)/2016 | |
DOI: 10.18698/1812-3368-2016-2-34-41 | |
Category: Physics | Chapter: Crystallography, Physics of Crystals | |
Keywords: diffraction pattern, crystallographic equivalent orientation, Ewald construction |
When doing diffraction studies of multiphase alloys, it is necessary to decrypt the diffraction patterns comprising a great number of phase reflexes formed by crystallographic equivalently oriented in the matrix phase separation. Similar problems can be solved by constructing a three-dimensional space model of reciprocal lattice points of the matrix and phase, taking into account all crystallographic equivalent phase orientations in the matrix. The central section of such a model corresponds to the electron-diffraction pattern, received in a transmission electron microscope. It is possible to obtain any zone axis in the section if the model is properly rotated in the reciprocal space. The ability to control the reflection of crystallographic equivalent phase orientations in the model makes it possible to split the reflexes of the various phases and their crystallographic equivalent orientation in any zone axes.
References
[1] Alekseev A.A., Anan’ev V.N., Ber L.B., Kaputkin E.Ya. Structure of Hardening Precipitates Formed during High-Temperature Aging in Alloys of Al-Cu-Mg System. Fizika metallov i metallovedenie [The Physics of Metals and Metallography], 1993, vol. 75, iss. 3, pp. 81-90 (in Russ.).
[2] Kablov E.N. Science of Aeronautical Materials: Results and Prospects. Vestnik RAN [Herald of the Russian Academy of Sciences], 2002, vol. 72, no. 1, pp. 3-12 (in Russ.).
[3] Kablov E.N. Strategical Areas of Developing Materials and Their Processing Technologies for the Period up to 2030. Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2012, no. 8, pp. 7-17 (in Russ.).
[4] Chabina E.B., Alekseev A.A., Filonova E.V., Lukina E.A. The Use of Methods of Analytical Microscopy and X-Ray Diffraction Analysis for the Study of the Structural Phase State Materials. Trudy VIAM [Electronic scientific journal Proceedings of VIAM], 2013, no. 5. Available at: http://viam-works.ru/plugins/content/journal/uploads/articles/pdf/37.pdf
[5] Orlov M.R. Strategical Development Tendencies of VIAM FSUE Testing Center. Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2012, no. 8, pp. 387-393.
[6] Kablov E.N., Ospennikova O.G., Vershkov A.V. Rare metals and rare-earth elements - materials for modern and future high technologies. Trudy VIAM [Electronic scientific journal Proceedings of VIAM], 2013, no. 2. Available at: http://viam-works.ru/plugins/content/journal/uploads/articles/pdf/9.pdf
[7] Oglodkov M.S., Khokhlatova L.B., Kolobnev N.I., Alekseev A.A., Lukina E.A. Effect of the thermomechanical treatment on Al (Al-Cu-Mg-Li-Zn) alloy properties and structure. Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2010, no. 4, pp. 7-11 (in Russ.).
[8] Lukina E.A., Alekseev A.A., Antipov V.V. et al. Application of the diagrams of phase transformations during aging for optimizing the aging conditions for V1469 and 1441 Al-Li alloys. Russian Metallurgy [Metally], 2009, iss. 6, pp. 505-511.
[9] Kolobnev N.I., Khokhlatova L.B., Alekseev A.A., Lukina E.A., Samokhvalov S.V. An Effect of Chemical Composition and Heat Treatment on Phase Composition and Properties of Al-Cu-Li-Zn Alloy В1461 with Zr, Sc Additives. Proc. Conf. ICAA11, 2008. Aachen, Germany, pp. 234-240.
[10] Hirsch P.B., Howie A., Nicholson R.B., Pashley D.W., Whelan M.J. Electron Microscopy of Thin Crystals. London, Butterworths, 1965. 549 p.
[11] Treninkov I.A., Alekseev A.A., Zaytsev D.V. Structure of reciprocal lattice sites of a single-crystal Ni-based superalloy. The Physics of Metals and Metallography, 2012, vol. 113, no. 10, pp. 938-946.
[12] Pearson W.B. The crystal chemistry and physics of metals and alloys. N.Y-London-Sydney-Toronto, Wiley-Interscience, John Wiley & Sons, 1972. 806 p.
[13] Shchegoleva T.V., Rybalko O.F. Structure of Metastable S’-Phase in the Al-Li-Mg Alloy. Fizika metallov i metallovedenie [The Physics of Metals and Metallography], 1980, vol. 50, iss. 1, pp. 86-90 (in Russ.).