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Hydrogen Concentration Measurement in a Flow using the Thermoconductivity Sensors

Authors: Bocharnikov V.M., Volodin V.V., Golub V.V., Dentsel N.K., Elyanov A.E. Published: 26.11.2025
Published in issue: #5(122)/2025  
DOI:

 
Category: Physics | Chapter: Instrumentation and Methods of Experimental Physics  
Keywords: hydrogen sensor, hydrogen safety, gas mixing, thermoelectronics, thermoconductivity

Abstract

The current trends in power development consider hydrogen as a promising power carrier. However, despite its potential, serious safety concerns remain, particularly in the presence of leaks. The paper substantiates a method for measuring hydrogen concentration in the hydrogen-air mixture flow using an assembly that consists of two thermoconductivity sensors. Introduction of the "open" sensor positioned along the flow and the "closed" sensor with a permeable mesh in a single assembly makes it possible to obtain a set of parameters for computing the mixture flow rate and the hydrogen concentration. The paper presents design of the measuring assemblies and provides results of the calibration experiments over an absolute pressure range of 0 to 5 atm, flow velocity of 0 to 1.84 m/s, and hydrogen concentration of 0 to 100 % (vol.). Experimental results demonstrate that using readings from the two thermoconductivity sensors and the pressure sensor makes it possible to unambiguously determine values of the hydrogen flow rate and concentration in the air-hydrogen mixture at the sensors' position. Such assemblies could be applied both for the laboratory purposes and in detecting gas mixture leaks in the emergencies

The work was financially supported by the Russian Science Foundation (grant no. 23-29-00267)

Please cite this article in English as:

Bocharnikov V.M., Volodin V.V., Golub V.V., et al. Hydrogen concentration measurement in a flow using the thermoconductivity sensors. Herald of the Bauman Moscow State Technical University, Series Natural Sciences, 2025, no. 5 (122), pp. 55--71 (in Russ.). EDN: UIQXRE

References

[1] Tuponosov F.V., Artemov V.I., Yankov G.G., et al. Numerical analysis of efficiency of mixing the fuel gases in a T-joint with the lateral pipe diameter and its insertion angle alteration. Herald of the Bauman Moscow State Technical University, Series Natural Sciences, 2024, no. 3 (114), pp. 115--132 (in Russ.). EDN: SEFVZP

[2] Kolesnichenko I.N., Platonov I.A., Novikova E.A., et al. Gas mixtures of the known composition by dynamic methods. Sorbtsionnye i khromatograficheskie protsessy, 2017, vol. 17, no. 3, pp. 378--387 (in Russ.). DOI: https://doi.org/10.17308/sorpchrom.2017.17/391

[3] Kuleshov F.S., Golovastov S.V., Bivol G.Yu. Influence of a porous polyurethane partition on hydraulic characteristics of the flow and on flame front propagation in an open channel. Herald of the Bauman Moscow State Technical University, Series Natural Sciences, 2022, no. 3 (102), pp. 110--123 (in Russ.). DOI: https://doi.org/10.18698/1812-3368-2022-3-110-123

[4] Volodin V.V., Golub V.V., Elyanov A.E., et al. Hydrogen-air flame propagation in a tube with heat-absorbing lining. Herald of the Bauman Moscow State Technical University, Series Natural Sciences, 2022, no. 5 (104), pp. 31--44 (in Russ.). DOI: https://doi.org/10.18698/1812-3368-2022-5-31-44

[5] Buttner W.J., Post M.B., Burgess R., et al. An overview of hydrogen safety sensors and requirements. Int. J. Hydrog. Energy, 2011, vol. 36, iss. 3, pp. 2462--2470. DOI: https://doi.org/10.1016/j.ijhydene.2010.04.176

[6] Li G., Du K., Wang X., et al. Pd nanoparticles decorated SnO2 ultrathin nanosheets for highly sensitive H2 sensor: experimental and theoretical studies. Int. J. Hydrog. Energy, 2024, vol. 50A, pp. 761--771. DOI: https://doi.org/10.1016/j.ijhydene.2023.06.263

[7] Roland U., Hebestreit A., Taoussanis A., et al. Cost-effective selective hydrogen sensor based on the combination of catalytic spillover effect and impedance measurement. Int. J. Hydrog. Energy, 2023, vol. 48, iss. 96, pp. 37550--37562. DOI: https://doi.org/10.1016/j.ijhydene.2022.12.302

[8] Zhang H., Zhu H., Su H., et al. High performance potentiometric hydrogen sensor based on ZnO porous cage sensing electrode. Int. J. Hydrog. Energy, 2024, vol. 54, pp. 1461--1468. DOI: https://doi.org/10.1016/j.ijhydene.2023.11.260

[9] Motora K.G., Dileepkumar V.G., Wu C.-M., et al. Highly efficient and stable NiSe2--rGO composite-based room temperature hydrogen gas sensor. Int. J. Hydrog. Energy, 2024, vol. 50A, pp. 1174--1183. DOI: https://doi.org/10.1016/j.ijhydene.2023.10.018

[10] Kim S., Song Y., Ahn H.-J., et al. Ultrafast response/recovery and high sensitivity of a hydrogen gas sensor at room temperature based on electrochemically deposited Sb2Te3/polystyrene composite film. Int. J. Hydrog. Energy, 2024, vol. 50, part A, pp. 959--972. DOI: https://doi.org/10.1016/j.ijhydene.2023.08.092

[11] Petrenko E.M., Semenova V.A. Alkaloids electrochemical multisensor express analysis in the electronic tongue format. Herald of the Bauman Moscow State Technical University, Series Natural Sciences, no. 6 (105), pp. 144--156 (in Russ.). DOI: https://doi.org/10.18698/1812-3368-2022-6-144-156

[12] Downes F., Taylor C.M. Theoretical investigation of a multi-channel optical fiber surface plasmon resonance hydrogen sensor. Opt. Commun., 2021, vol. 490, art. 126916. DOI: https://doi.org/10.1016/j.optcom.2021.126916

[13] Konyukhov A.I. A nondispersive optical gas sensor with time division multiplexing of reference and active signals. Pribory i tekhnika eksperimenta, 2023, no. 2, pp. 115--121 (in Russ.). DOI: https://doi.org/10.31857/S0032816223010184

[14] Alferov V.N., Vasilyev D.A. An acoustic gas analyzer. Instrum. Exp. Tech., 2020, vol. 63, no. 5, pp. 787--790. DOI: https://doi.org/10.1134/S0020441220050085

[15] Wang W., Liu X., Mei S., et al. Development of a Pd/Cu nanowires coated SAW hydrogen gas sensor with fast response and recovery. Sens. Actuators B: Chem., 2019, vol. 287, pp. 157--164. DOI: https://doi.org/10.1016/j.snb.2019.02.047

[16] Tasyurek L.B., Isik E., Isik I., et al. Enhancing the performance of TiO2 nanotube-based hydrogen sensors through crystal structure and metal electrode. Int. J. Hydrog. Energy, 2024, vol. 54, pp. 678--690. DOI: https://doi.org/10.1016/j.ijhydene.2023.08.202

[17] Vasiliev A., Shakhnovich I., Samotaev N., et al. Intellectual thermoconductometric unit based on aerosol printed ceramic MEMS sensor for the measurement of natural gas composition. Proceedings, 2018, vol. 2, iss. 13, art. 736. DOI: https://doi.org/10.3390/proceedings2130736

[18] Thermal mass flow sensor FS7. Application note. Switzerland, Ebnat-Kappel, IST, 2021.

[19] Sazhin O. Novel mass air flow meter for automobile industry based on thermal flow microsensor. I. Analytical model and microsensor. Flow Meas. Instrum., 2013, vol. 30, pp. 60--65. DOI: https://doi.org/10.1016/j.flowmeasinst.2013.01.006

[20] Tang Z., Yang Q., Yu Ch., et al. Measurement of gas-liquid flows with the combination of thermal sensors and conductance sensor. Flow Meas. Instrum., 2023, vol. 93, art. 102429. DOI: https://doi.org/10.1016/j.flowmeasinst.2023.102429